Mass spectrometry
I can explain how mass spectrometry is used to identify isotopes and molecular structures, and calculate relative atomic masses.
Mass spectrometry
I can explain how mass spectrometry is used to identify isotopes and molecular structures, and calculate relative atomic masses.
These resources will be removed by end of Summer Term 2025.
Lesson details
Key learning points
- Isotopes are atoms of the same element with different numbers of neutrons.
- Relative abundances of isotopes can be used to calculate the relative atomic mass (RAM) of an element.
- Mass spectrometry ionises samples to create positive ions for analysis.
- The M⁺ peak represents the molecular ion, indicating the molecular mass.
- Fragmentation in mass spectrometry helps identify molecular structure by breaking molecules into smaller ions.
Keywords
Isotope - An atom of an element with the same number of protons, but different number of neutrons.
Relative atomic mass - An average value that takes account of the abundance of the isotopes of the element.
Molecular mass - The sum of the atomic masses of all the atoms in a molecule.
Molecular ion - The ion produced when the molecule is ionised by loss of an electron from the molecule.
Spectrometer - An apparatus used for recording and measuring spectra, especially as a method of analysis.
Common misconception
All peaks in a mass spectrum represent intact (and neutral) molecules or atoms.
Clarify that in mass spectrometry, all detected peaks represent ionised species, not neutral molecules or atoms. The peaks can correspond to either the molecular ion (M⁺) or smaller ionised fragments, as well as different isotopes of an element.
To help you plan your year 11 chemistry lesson on: Mass spectrometry, download all teaching resources for free and adapt to suit your pupils' needs...
To help you plan your year 11 chemistry lesson on: Mass spectrometry, download all teaching resources for free and adapt to suit your pupils' needs.
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