New
New
Year 11
OCR
Higher

Chemical tests: aqueous ions (including zinc)

I can perform and interpret sodium hydroxide precipitate tests for metal ions and other tests for identifying ammonium, carbonate, sulfate, and halide ions.

New
New
Year 11
OCR
Higher

Chemical tests: aqueous ions (including zinc)

I can perform and interpret sodium hydroxide precipitate tests for metal ions and other tests for identifying ammonium, carbonate, sulfate, and halide ions.

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Lesson details

Key learning points

  1. Some metal ions form coloured precipitates in a reaction with sodium hydroxide solution.
  2. Ammonium ions can be identified by heating with NaOH and using damp red litmus paper, which turns blue if positive.
  3. A dilute acid is usually added before testing for carbonates, sulfates or halides to avoid false positives.
  4. Halide ions produce different coloured precipitates when silver nitrate is added to a solution containing them.
  5. A white precipitate is formed when barium chloride is added to an acidified solution containing sulfate ions.

Keywords

  • Precipitate - An insoluble solid formed when two solutions react together.

  • Ion - An ion is an atom or group of atoms with a positive or negative charge due to the loss or gain of electrons.

  • Cation - A positively charged ion.

  • Anion

Common misconception

All white precipitates in chemical tests indicate the presence of the same ion without the need for further testing.

Explain that white precipitates can indicate different ions depending on the test. For instance, barium sulfate indicates sulfate ions, silver chloride indicates chloride ions, and sodium hydroxide tests distinguish between cations.

Emphasise the importance of following proper procedures for each specific test, including using the correct reagents and conditions, to avoid confusion and ensure accurate results.
Teacher tip

Equipment

NaCl, CaSO₄, Na₂SO₄, BaCl₂, HCl, AgNO₃, HNO₃, pipettes, test tubes, test tube racks, limewater, delivery tubes, bungs, boiling tubes

Content guidance

  • Risk assessment required - chemicals
  • Risk assessment required - equipment

Supervision

Adult supervision required

Licence

This content is © Oak National Academy Limited (2024), licensed on Open Government Licence version 3.0 except where otherwise stated. See Oak's terms & conditions (Collection 2).

Lesson video

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6 Questions

Q1.
Which particle does an atom lose or gain one or more of to form an ion?
proton
Correct answer: electron
neutron
Q2.
What does litmus paper indicate?
the concentration of ions in a solution
the presence of metal ions
Correct answer: whether a solution is acidic or basic
the pH value of a solution
Q3.
What is the charge of a cation?
Correct answer: positive
negative
neutral
Q4.
Which of the following is a common laboratory acid?
ethanoic acid
Correct answer: hydrochloric acid
carbonic acid
citric acid
Q5.
Which of the following are basic laboratory techniques?
Correct answer: heating solutions
Correct answer: performing chromatography
using a spectrometer
Q6.
What does a basic understanding of chemical reactions include?
Correct answer: knowing how to write and balance chemical equations
understanding complex organic synthesis
using advanced analytical techniques

6 Questions

Q1.
What colour precipitate does copper(II) form with sodium hydroxide?
Correct answer: blue
brown
green
yellow
Q2.
Which gas is released when ammonium ions are heated with sodium hydroxide?
Correct answer: ammonia
hydrogen
oxygen
carbon dioxide
Q3.
What colour does damp red litmus paper turn in the presence of ammonia gas?
purple
green
Correct answer: blue
it doesn't change colour
Q4.
What colour precipitate is formed when silver nitrate is added to a solution containing chloride ions?
cream
Correct answer: white
yellow
grey
Q5.
Why is dilute nitric acid added before testing for halides?
to enhance the colour of the precipitate
Correct answer: to remove any carbonates that might interfere with the test
to neutralise the solution
to form halide ions in solution
Q6.
What precipitate is formed when barium chloride is added to an acidified solution containing sulfate ions?
green
blue
Correct answer: white
brown